Preparation of Metallosilicates with ZSM-5 Type Structure by Atom-Planting Method

Organosilane with gemini-type structure as the mesoporogen for synthesis of hierarchical porous ZSM-5 zeolite

A new kind of organosilane (1,6-bis (diethyl(3-trimethoxysilylpropyl)ammonium) hexane bromide) with a geminitype structure was prepared and used as a mesoporogen for the synthesis of hierarchical porous ZSM-5 zeolite. There are two quaternary ammonium centers along with double hydrolysable -RSi(OMe)3 fragments in the organosilane, which results in a strong interaction between this mesoporogen a...

Structure of toluene6.4-ZSM-5 and the toluene disproportionation reaction on ZSM-5.

The structure of a high-loading complex of ZSM-5 with 6.4 toluene molecules per unit cell has been determined by single-crystal X-ray diffraction. At least three kinds of toluene molecules were identified in the unit cell. Two disordered toluene molecules were located at the intersection of the straight and sinusoidal channels, the third in the sinusoidal channel. One (TOL1) of the two toluene ...

Preparation of Zsm-5 Zeolite Membranes by Combined Hydrothermal Synthesis and Electrophoretic Deposition

Preparation of H-ZSM-5 Nano-Zeolite Using Mixed Template Method and its Activity Evaluation for ethanol to DME Reaction

H-ZSM-5 nano-zeolites were synthesized by hydrothermal method using tetrapropylammonium hydroxide (TPAOH) as a template in the presence of various TPABr concentrations. The effect of different TPABr/TPAOH molar ratios was studied on the catalytic performance of dehydration of methanol to dimethyl ether (DME) in a fixed bed reactor under the same operating conditions (T=300°C, P=1 atm, and WHSV=...

A Non-Demolition Photon Counting Method by Four-Level Inverted Y-Type Atom

The semi-classical model of atom-field interaction has been fully studied for some multilevel atoms, e.g. Vee, L, Cascade X , Y, and inverted Y and so on. This issue is developed into the full-quantum electrodynamics formalism, where the probe and coupling electromagnetic fields are quantized. In this article, we investigate the full-quantum model of absorption and dispersion spectrum of trappe...